(μ-Diphenylphosphanido-κ2 P:P′)bis[2,2′-(pyridine-2,6-diyl)diphenyl-κ3 C 1,N,C 1′)gold(III)] perchlorate acetonitrile solvate
نویسندگان
چکیده
The title complex, [Au(2)(C(17)H(11)N)(2)(C(12)H(10)P)]ClO(4)·C(2)H(3)N, contains two Au(III) atoms bridged by a diphenyl-phosphanide ligand. Each Au atom is in a square-planar environment coordinated by diphenyl-phosphanide and 2,6-diphenyl-pyridine ligands. There are weak π-π stacking inter-actions between neighbouring mol-ecules (the inter-planar separations between two neighbouring dpp units are 3.40 and 3.57 Å). The intra-molecular Au⋯Au separation is 3.788 (5) Å. The crystal structure shows weak inter-molecular C-H⋯O and C-H⋯N hydrogen bonds involving an O atom of the perchlorate counter-ion and the N atom of the acetonitrile solvent mol-ecule, respectively.
منابع مشابه
Tris(2,2′-bipyridine-κ2 N,N′)cobalt(III) bis[bis(pyridine-2,6-dicarboxylato-κ3 O 2,N,O 6)cobaltate(III)] perchlorate dimethylformamide hemisolvate 1.3-hydrate
In the title compound, [Co(C(10)H(8)N(2))(3)][Co(C(7)H(3)NO(4))(2)](2)(ClO(4))·0.5C(3)H(7)NO·1.3H(2)O, the Co(III) atom in the complex cation is pseudoocta-hedrally coordinated by six N atoms of three chelating bipyridine ligands. The Co(III) atom in the complex anion is coordinated by two pyridine N atoms and four carboxyl-ate O atoms of two doubly deprotonated pyridine-2,6-dicarboxyl-ate liga...
متن کامل{μ-N-[(Diphenylphosphino)methyl]pyridin-2-amine-κ2 N 1:P}bis{[2-(2,2′-bipyridin-6-yl)phenyl-κ3 N,N′,C 1]platinum(II)} bis(perchlorate)
The title compound, [Pt(2)(C(16)H(11)N(2))(2)(C(18)H(17)N(2)P)](ClO(4))(2), contains two Pt(II) atoms, bridged by an N-[(diphenyl-phosphino)meth-yl]pyridin-2-amine (dppmp) ligand. One Pt atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2'-bipyridine (pbpy) ligand in a square-planar geometry. The other Pt atom is coordinated by one N atom ...
متن کامل(4′-Allyloxy-2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)(dibenzoylmethanido-κ2 O,O′)bis(nitrato-κ2 O,O′)neodymium(III) acetonitrile solvate
The title complex, [Nd(C(15)H(11)O(2))(NO(3))(2)(C(18)H(15)N(3)O)]·CH(3)CN or [Nd(altpy)(dbm)(NO(3))(2)]·CH(3)CN (altpy = 4'-all-yl-oxy-2,2':6',2''-terpyridine, dbm = dibenzoyl-methanide anion), has been synthesized from 4'-all-yloxy-2,2':6',2''-terpyridine, dibenzoyl-methanate and neodymium nitrate. The Nd(3+) atom is nine-coordinated by two O atoms from the bidentate dbm ligand, three N atoms...
متن کامل(4′-Ferrocenyl-2,2′:6′,2′′-terpyridine-κ3 N 1,N 1′,N 1′′)(1,10-phenanthroline-κ2 N,N′)zinc(II) bis(perchlorate) acetonitrile monosolvate
In the title complex, [FeZn(C(5)H(5))(C(20)H(14)N(3))(C(12)H(8)N(2))](ClO(4))(2)·CH(3)CN, the Zn(II) atom is five-coordinated by a tridentate chelating 4'-ferrocenyl-2,2':6',2''-terpyridine (fctpy) ligand and a bidentate chelating 1,10-phenanthroline (phen) ligand in a distorted square-pyramidal environment with a phen N atom located at the apical position [Zn-N = 2.259 (4) Å]. The terpyridyl m...
متن کاملcatena-Poly[[[acetonitrilecopper(I)]-bis[μ-bis(diphenylphosphino)methane-κ2 P:P′]-copper(I)-μ-1,2-di-4-pyridylethene] bis(tetrafluoridoborate)]
The title dinuclear copper(I) complex, {[Cu(2)(C(2)H(3)N)(C(12)H(10)N(2))(C(25)H(22)P(2))(2)](BF(4))(2)}(n), contains 1,2-di-4-pyridyl-ethene, bis-(diphenyl-phosphino)methane and acetonitrile ligands. The two Cu atoms, one with an N(2)P(2) ligand set and the other with an NP(2) ligand set, are bridged by two bis-(diphenyl-phosphino)methane ligands, forming an eight-membered ring.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008